In ANSYS, there is no such saying as unit system except for electromagnetic modeling , so you just keep using a a single unit system throughout your problem.
say:
1) if a line in your proe model is 3mm in length, it is 3 (no unit) in the ansys model.
2) assuming that you appllied a concentrated force load at a node, say 2N
3) the unit of your result will be N/mm^2